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Beilstein J. Org. Chem. 2019, 15, 1441–1447, doi:10.3762/bjoc.15.144
Graphical Abstract
Figure 1: Structures of trifluoromethyl sulfonyl ether bioactives.
Figure 2: Comparison of log P values of comparative aryl thioether motifs [18].
Figure 3: α,α-Difluoroethyl thioether substrates for metabolism studies.
Scheme 1: Fluorometabolites 6–8 isolated after incubation of 4 with C. elegans. Ratios are the average of thr...
Scheme 2: Putative pathways for (α,α-difluoroethyl)(4-methoxyphenyl)sulfane (4) metabolism.
Scheme 3: C. elegans incubation of 5. Ratios are the average of three incubations.
Scheme 4: Incubation (four times) of oxygen ether 14 with C. elegans, gave 4-acetoxyphenol (15) as the major ...
Beilstein J. Org. Chem. 2014, 10, 1099–1106, doi:10.3762/bjoc.10.108
Scheme 1: Representative examples of multisubstituted CF3-alkenes.
Scheme 2: Catalytic synthesis of CF3-alkenes via trifluoromethylation.
Scheme 3: Our strategies for synthesis of CF3-alkenes.
Scheme 4: Synthesis of geminal bis(trifluoromethyl)alkenes.
Scheme 5: A possible reaction mechanism.
Figure 1: Time profile of the photocatalytic trifluoromethylation of 2a with 1a with intermittent irradiation...